Synthesis of Copper(I) Catenanes Incorporating a Disulfide Bridge and Their Deposition on a Gold Surface
- 13 June 2000
- journal article
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 2 (14) , 1991-1994
- https://doi.org/10.1021/ol005774z
Abstract
The synthesis of two coordinating catenates with the ability to undergo surface-confined chemistry is described. For each catenate, one of the rings includes a 2,9-diphenyl-1,10-phenanthroline unit as a coordinating moiety and a disulfide bridge, which allows adsorption of the catenate onto a gold surface, thus going from a molecular catenate to a [gold-adsorbed] species in which gold atoms are elements of one of the rings.Keywords
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