On the Interaction Between the A2Π and B2Σ States of the CaCl Molecule
- 1 July 1981
- journal article
- Published by IOP Publishing in Physica Scripta
- Vol. 24 (1A) , 25-29
- https://doi.org/10.1088/0031-8949/24/1a/006
Abstract
A deperturbation of the interaction between the A 2Π and B 2Σ states in CaCl is presented. The results are used to determine the mixing coefficients in a 4p, 3d, 4f Ca+ orbital hybridization model for the low lying electronic states in CaCl. These mixing coefficients are used in the interaction calculation to predict the equilibrium energy of the hitherto unobserved 2Δ molecular state. The mixing coefficients obtained are close to the ones predicted from the model of polarizable ions where the A and B states correlate to the Ca+ (2D) + Cl- (2S) states of the separated ions.Keywords
This publication has 33 references indexed in Scilit:
- Laser Spectroscopic Investigations of CaClPhysica Scripta, 1980
- A Study of theX2Σ Potential Energy Curve of the Gaseous Calcium Chloride MoleculePhysica Scripta, 1980
- Laser Spectroscopic Investigations of CaCl. II. Rotational Analysis of the B2Σ- X2Σ TransitionsPhysica Scripta, 1980
- Rotational analysis of the A2Π-X2Σ system of SrF using a CW tunable dye laserJournal of Molecular Spectroscopy, 1978
- Observations of Two Photon Absorption in Gaseous CaCl. A Study of theD2Σ and X2Σ StatesPhysica Scripta, 1978
- Microwave optical double resonance and reanalysis of the CaF A2Πr-X2Σ band systemJournal of Molecular Spectroscopy, 1978
- A study of the A 2Π-X2Σ+ system of CaCl by saturation spectroscopyChemical Physics Letters, 1978
- The rotational spectrum of the state of the SrF radical using laser microwave optical double resonanceJournal of Molecular Spectroscopy, 1977
- Rotational analysis of the system of SrF using a cw tunable dye laserJournal of Molecular Spectroscopy, 1977
- The rotational spectrum of the X2Σ+ state of the Ca35Cl radical using laser microwave optical double resonanceJournal of Molecular Spectroscopy, 1977