Raman study of CF4 in liquid Ar
- 1 January 1983
- journal article
- research article
- Published by Taylor & Francis in Molecular Physics
- Vol. 49 (6) , 1375-1384
- https://doi.org/10.1080/00268978300102011
Abstract
The rotational behaviour of CF4 dissolved in liquid argon is derived from the band contour analysis of Raman spectra recorded over the concentration range from 10-2 mole fraction to 1 mole fraction at 85 K. The angular momentum correlation times have been determined with the help of the J-diffusion model and used to apply the rough hard sphere model. A study of the transition dipole-transition dipole (TD-TD) interaction is made using the v 3 mode at 85 K for different concentrations.Keywords
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