Ion cyclotron resonance bridge detector for frequency sweep

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Abstract
An electronic ion cyclotron resonance detection system was designed and constructed. The ions are excited by sweeping the frequency of the electric field (3–300 kHz) using a sweep frequency generator with a nonlinear sweep voltage in order to maintain an approximately constant mass resolution. Ion detection is accomplished by a bridge with a phase-sensitive detector as a demodulator. The required reference signal for the phase-sensitive detector is generated by a circuit with a transfer function which approximates that of the ICR signal in order to obtain an accurate phase match between the signal source and the detector. The device is capable of detecting a minimum concentration of 50 ions/cm3 over a mass range of 15 to 1500 amu.