Pentamacrocyclic tris-crown hosts: selective binding of cationic, anionic, and neutral guests
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 2,p. 158-161
- https://doi.org/10.1039/c39900000158
Abstract
The tris-crown host compounds (1)–(4) were synthesized and the structures of (2) and of the 3:1 potassium complex of (1)(with the SCN- anion projecting inside the cavity) were studied by X-ray analyses; specific organic guest molecules like β-naphthol and naphthalene diols are selectively bound inside the fitting cavities of the hosts (2) and (3)[but not (1) and (4)] in acidic water solution.Keywords
This publication has 14 references indexed in Scilit:
- Molecular recognition by macropolycyclic hostsJournal of inclusion phenomena and molecular recognition in chemistry, 1989
- Selektive molekulare Erkennung und Trennung isomerer und partiell hydrierter AreneAngewandte Chemie, 1987
- Selective Molecular Recognition and Separation of Isomeric and Partially Hydrogenated ArenesAngewandte Chemie International Edition in English, 1987
- Cyclodextrine und synthetische Wirthohlräume — Vergleich der KomplexierungseigenschaftenJournal of Inclusion Phenomena, 1985
- Neue Wirtmoleküle verschiedener Hohlraumgröße zur Komplexierung organischer GastmoleküleThe Science of Nature, 1985
- Coreceptor–substrate binding. Crystal structures of a macrotricyclic ligand and of its molecular cryptate with the cadaverine dicationJournal of the Chemical Society, Chemical Communications, 1982
- Synthesis and ammonium cryptates of triply bridged cylindrical macrotetracyclesJournal of the American Chemical Society, 1981
- The crystal and molecular structure of 4-nitrobenzo-1,4,7,10,13,16-hexaoxacyclooctadecane. RbSCN, C17H23O8N2SRbActa Crystallographica Section B: Structural Science, Crystal Engineering and Materials, 1978
- Caesium thiocyanate complex of 1,4,7,10,13,16-hexaoxacyclooctadecaneActa Crystallographica Section B: Structural Science, Crystal Engineering and Materials, 1974
- Rubidium thiocyanate complex of 1,4,7,10,13,16-hexaoxacyclooctadecaneActa Crystallographica Section B: Structural Science, Crystal Engineering and Materials, 1974