Molecular Ions in Radiation Chemistry. II. Aromatic-Hydrocarbon Cations in CCl4 at 77°K
- 15 March 1966
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 44 (6) , 2375-2377
- https://doi.org/10.1063/1.1727051
Abstract
Solutions of aromatic hydrocarbons in a polycrystalline matrix of CCl4 at 77°K have been γ irradiated and well‐resolved optical absorption spectra measured in the interval 270–2000 mμ. All spectra characteristic of solute are attributed to molecular monopositive ions of benzene, toluene, bi‐ and triphenyl methanes, biphenyl, o‐, m‐, and p‐terphenyl, bi‐, tri‐, and tetraphenylethylene, biphenylacetylene, naphthalene, anthracene, phenanthrene, stilbene, diphenylstibene, and 1,3,5‐triphenylbenzene. Resonance charge transfer from CCl4+ to CCl4, terminated by transfer from CCl4+ to solute, is postulated.Keywords
This publication has 20 references indexed in Scilit:
- The radiation chemistry of low temperature methanolic glassesProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1965
- Electron Capture Processes in the γ-Radiation of Organic Halides in Hydrocarbon Rigid MatricesJournal of the American Chemical Society, 1964
- Electron Attachment and Solvation in Gamma Irradiated Organic Glasses at - 196°Journal of the American Chemical Society, 1962
- Electron Spin Resonance Spectra of Aromatic Mononegative and Monopositive Ions1Journal of the American Chemical Society, 1958
- On the Interpretation of the Electron Spin Resonance Spectra of Solutions of Hydrocarbons in Sulfuric AcidThe Journal of Chemical Physics, 1957
- Electronic spectra of mono‐ and di‐negative aromatic ionsRecueil des Travaux Chimiques des Pays-Bas, 1957
- The electronic spectra of aromatic hydrocarbon anionsRecueil des Travaux Chimiques des Pays-Bas, 1957
- Electronic spectra of alternant hydrocarbon mononegative ionsRecueil des Travaux Chimiques des Pays-Bas, 1957
- Properties of hydrocarbon monopositive ionsRecueil des Travaux Chimiques des Pays-Bas, 1957
- Reaction of Sodium Metal with Aromatic Hydrocarbons1,2Journal of the American Chemical Society, 1956