The Modulating Possibilities of Dicarbollide Clusters: Optimizing the Kharasch Catalysts
- 9 September 2003
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 125 (39) , 11830-11831
- https://doi.org/10.1021/ja036342x
Abstract
exo-Cluster dicarbollides substitution has allowed tuning of the E° (Ru(II)/Ru(III)) potential to obtain the best-performing Kharasch catalyst. We postulate that this is possible through the to-and-fro electron movement between the boron cluster and the sulfonium moieties.Keywords
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