Electronic Transport in Metal Nanocrystal Arrays: The Effect of Structural Disorder on Scaling Behavior

We investigate the impact of structural disorder on electronic transport in gold nanocrystal monolayers. Arrays ranging from void-filled networks to well-ordered superlattices show clear voltage thresholds $\left(V_{\mathrm{T}}\right)$ due to Coulomb blockade, and temperature-independent conduction indicative of quantum tunneling. Current-voltage characteristics of arrays with and without long-range structural order were found to collapse onto distinct scaling curves. The former follow a single power law: $I\sim ({V-V}_{\mathrm{T}}{)}^{\zeta }$, $\zeta =2.25\mathrm{}\pm 0.1$. The latter show additional structure, reflecting the underlying disordered topology.