Robust solutions of the Yvon-Born-Green equation at very high densities
- 1 November 1989
- journal article
- research article
- Published by Taylor & Francis in Molecular Physics
- Vol. 68 (4) , 791-802
- https://doi.org/10.1080/00268978900102551
Abstract
The Yvon-Born-Green equation under the Kirkwood superposition closure is solved for a system of hard spheres at very high densities, using a robust (second-order) convergence routine. As witnessed in earlier studies, a transition from damped oscillatory g (2)(x) functions to undamped periodic g (2)(x) functions is observed at a given value of the density parameter. However, the nature and the multiplicity of the high density solutions using the robust technique and presented herein are significantly different than before, presumably due to inadequate convergence of the earlier high density solutions.Keywords
This publication has 9 references indexed in Scilit:
- The influence of closure on the behaviour of the Yvon-Born-Green equation for a system of hard rodsMolecular Physics, 1982
- A variational approach to the statistical mechanics of hard discs and hard spheresMolecular Physics, 1981
- Solutions of the Yvon-Born-Green equation for hard discs at very high densitiesMolecular Physics, 1981
- Solutions of the Yvon–Born–Green and Kirkwood equations for hard spheres at very high densitiesThe Journal of Chemical Physics, 1977
- Solutions of the Yvon–Born–Green equation for the square-well fluid at very high densitiesThe Journal of Chemical Physics, 1976
- Properties of solutions to the Yvon–Born–Green equation for the square-well fluidThe Journal of Chemical Physics, 1975
- Radial Distribution Functions and the Equation of State of Fluids Composed of Molecules Interacting According to the Lennard-Jones PotentialThe Journal of Chemical Physics, 1952
- Radial Distribution Functions and the Equation of State of a Fluid Composed of Rigid Spherical MoleculesThe Journal of Chemical Physics, 1950
- Statistical Mechanics of FusionThe Journal of Chemical Physics, 1941