The Spectrum of Deuteroacetone in the Vacuum Ultraviolet A Comparison with the Spectrum of Acetone
- 1 August 1944
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 12 (8) , 329-335
- https://doi.org/10.1063/1.1723951
Abstract
The spectrum of acetone‐d6 of over 90 percent purity has been photographed in the region 2000–1300A, with a dispersion of 4.14A per mm. Data for the transition at about 51,000 cm−1 are presented together with new data on acetone in the same region. A discussion of the normal state of the acetones is given, and an analysis is made of the electronic spectra. It is shown that no vibrational frequency near 1200 cm−1 appears in the excited state of acetone‐d6 and that this frequency in acetone cannot be ascribed to the C–O vibration.Keywords
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