Linear Chain Compounds of Molybdenum(II) Acetate Linked by Pyrazine, 4,4′-Bipyridine, and 1,4-Diazabicyclo[2.2.2]octane
- 1 September 1995
- journal article
- research article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 68 (9) , 2567-2572
- https://doi.org/10.1246/bcsj.68.2567
Abstract
A series of linear-chain complexes of molybdenum(II) acetate linked by bidentate bridging ligands, [Mo-2(O2CCH3)(4)L](n) (L=pyrazine (pyz), 4,4'-bipyridine (4,4'-bpy), and 1,4-diazabicyclo[2.2,2]octane (dabco)), have been prepared, and their crystal structures determined by an X-ray diffraction method. It has been shown that the relatively weak coordinations of the bridging ligands at the axial positions of Mo-2(O2CCH3)4 (Mo-N=2.619 (8)-2.658(6) Angstrom) can effectively control the arrangement of the dimer units to give chain structures with good linearities. No significant interactions between the dimer units have been observed.This publication has 27 references indexed in Scilit:
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