Synthesis and Properties of Conducting Bridged Macrocyclic Metal Complexes
- 1 July 1983
- journal article
- research article
- Published by Taylor & Francis in Molecular Crystals and Liquid Crystals
- Vol. 96 (1) , 263-270
- https://doi.org/10.1080/00268948308074709
Abstract
The synthesis and the properties of polymeric phthalocyaninatometal complexes of the type shown in figure 1 are described. In addition to pyrazine (pyz) and 1, 4-diisocyanobenzene (dib) the cyano-group is used as a bridging ligand for the first time such leading to μ-cyanophthalocyaninatocobalt(III) (10). 10 shows a conductivity of 10−2 S · cm−1 (powder, compressed pellets) at room temperature without iodine-doping.Keywords
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