Surface phase transitions in polymer systems
- 1 January 1993
- journal article
- research article
- Published by American Physical Society (APS) in Reviews of Modern Physics
- Vol. 65 (1) , 87-113
- https://doi.org/10.1103/revmodphys.65.87
Abstract
Self-avoiding walks, lattice trees, and related geometrical models provide a link between the physics of polymers and the study of critical phenomena. In particular, these models in the presence of a surface provide insight into surface adsorption in dilute polymer systems in a good solvent. The theme of this review is the influence of polymer structure (topology) on the critical properties of these models. Emphasis is placed on recent results by rigorous methods, scaling theory, and conformal covariance theory. Numerical results that may be used to test the predictions of scaling of scaling and conformal covariance theories are also summarized. Related topics such as the adsorption of directed polymers, the semidilute regime, the theta point and theta solvents, and percolation (polymer gels) are briefly discussed in the final section.Keywords
This publication has 106 references indexed in Scilit:
- Models for the surface adsorption of triblock copolymersMacromolecules, 1990
- Branched polymers in a wedge geometry in three dimensionsJournal of Statistical Physics, 1990
- Statistical mechanics of polymer networks of any topologyJournal of Statistical Physics, 1989
- θ point of a linear polymer in 2 dimensions: a renormalization group analysis of Monte Carlo enumerationsJournal de Physique, 1988
- Universal amplitude ratios for the surface tension of polymer solutionsThe Journal of Chemical Physics, 1984
- Dilute and semidilute polymer solutions near an adsorbing wallThe Journal of Chemical Physics, 1983
- Analysis and dilute solution properties of 12- and 18-arm-star polystyrenesMacromolecules, 1983
- Self-avoiding walks with geometrical constraintsJournal of Statistical Physics, 1983
- Dynamic measurements on polymer chain dimensions below the θ-temperatureJournal de Physique, 1982
- Short range correlation between elements of a long polymer in a good solventJournal de Physique, 1980