EFFECTIVE ASYMMETRIC HYDROGENATION OF DEHYDRODIPEPTIDES WITH RHODIUM(I)-NEW CHIRAL DIPHOSPHINITE SYSTEMS
- 5 August 1983
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 12 (8) , 1203-1206
- https://doi.org/10.1246/cl.1983.1203
Abstract
Rh(I)-new chiral diphosphinite systems with terminal amino groups were very effective for asymmetric hydrogenation of dehydrodipeptides with free carboxyl group and a chiral carbon. The effectiveness of the diphosphinite catalysts strongly suggests the contribution of electrostatic effect to asymmetric induction.This publication has 7 references indexed in Scilit:
- Synthesis of chiral dipeptides by means of asymmetric hydrogenation of dehydro dipeptidesThe Journal of Organic Chemistry, 1982
- Asymmetrische Katalysen, V. Enantioselektive Aminosäuresynthese durch Hydrierung prochiraler Olefine mit Rh‐Komplexen des neuen optisch aktiven chelatbildenden Phosphans NorphosEuropean Journal of Inorganic Chemistry, 1981
- Synthesis of 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl (BINAP), an atropisomeric chiral bis(triaryl)phosphine, and its use in the rhodium(I)-catalyzed asymmetric hydrogenation of .alpha.-(acylamino)acrylic acidsJournal of the American Chemical Society, 1980
- Stereoselective synthesis of dipeptides by asymmetric reduction of dehydropeptides catalyzed by chiral rhodium complexesThe Journal of Organic Chemistry, 1980
- Modification of (S)-N,N-Dimethyl-1-[(R)-1′,2-bis(diphenylphosphino)ferrocenyl]ethylamine (BPPFA) as a Ligand for Asymmetric Hydrogenation of Olefins Catalyzed by a Chiral Rhodium(I) ComplexBulletin of the Chemical Society of Japan, 1980
- Asymmetric synthesis. Production of optically active amino acids by catalytic hydrogenationJournal of the American Chemical Society, 1977
- Asymmetric hydrogenation. Rhodium chiral bisphosphine catalystJournal of the American Chemical Society, 1977