The correlation of theã,3A2state of CS2with states of linear CS2
- 1 January 1973
- journal article
- research article
- Published by Taylor & Francis in Molecular Physics
- Vol. 25 (1) , 137-144
- https://doi.org/10.1080/00268977300100151
Abstract
It is shown from gas phase band intensity measurements that the ã - X system of CS2 is vibronically induced with a transition moment proportional to the second power of the bending normal coordinate of the linear ground state. Hence it is deduced that the ã, 3 A 2 state of bent CS2 is derived from the 2 u component of a 3Δ u state of linear CS2. This orbital nature of the ã state is also consistent with the observed Zeeman effect.Keywords
This publication has 10 references indexed in Scilit:
- Theoretical Interpretation of the Zeeman Effect in the Near-Ultraviolet Bands of CS2The Journal of Chemical Physics, 1964
- Zeeman Effect and Rotational Analyses of the Near-Ultraviolet Bands of CS2The Journal of Chemical Physics, 1964
- THE NEAR-ULTRAVIOLET ABSORPTION SPECTRUM OF CS2Canadian Journal of Physics, 1963
- Note on the magnetic rotation spectrum of CS2Journal of Molecular Spectroscopy, 1963
- Theory of the Renner effect in the NH2radicalMolecular Physics, 1958
- THE LOWER EXCITED STATES OF SOME SIMPLE MOLECULESCanadian Journal of Chemistry, 1958
- 467. The electronic orbitals, shapes, and spectra of polyatomic molecules. Part II. Non-hydride AB2 and BAC moleculesJournal of the Chemical Society, 1953
- The Experimental Determination of the Intensities of Infra-Red Absorption Bands I. Theory of the MethodThe Journal of Chemical Physics, 1946
- Correlation of Energy Levels of Linear and Bent Triatomic Molecules, and the Ultraviolet CAbsorption SpectrumPhysical Review B, 1941
- The Magnetic Rotation Spectra of Sand Cin the UltravioletPhysical Review B, 1939