Enantioselective α-hydrogen-atom abstraction from an ester by an optically active amine-boryl radical
- 1 January 1991
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 150-152
- https://doi.org/10.1039/c39910000150
Abstract
The optically active amine-boryl radical IpcḂH â†� NMe2CH2CH2NMe2→ BH2Ipc (Ipc = isophinocampheyl)abstracts hydrogen enantioselectively from the α-C–H group of methyl 2-phenylpropanoate; partial kinetic resolution of the ester has been achieved in a catalytic manner.Keywords
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