The microwave spectrum and molecular structure of CO2–HCl
- 1 November 1982
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 77 (9) , 4344-4349
- https://doi.org/10.1063/1.444424
Abstract
Radio frequency and microwave molecular beam electric resonance spectra have been obtained for three isotopic species of the hydrogen‐bonded weakly bound complex CO2–HCl. The following spectroscopic constants have been determined: This complex most likely has a linear equilibrium geometry with an O–H bond length of 2.14 Å. A large induced dipole moment is found in this complex. A comparison of structural properties for this and other related weakly bound molecules is made.Keywords
This publication has 22 references indexed in Scilit:
- Microwave and radio frequency spectra of Xe–HFThe Journal of Chemical Physics, 1981
- The structure of N2O–HFThe Journal of Chemical Physics, 1981
- Microwave rotational spectrum, molecular geometry, and intermolecular interaction potential of the hydrogen-bonded dimer OC–HClThe Journal of Chemical Physics, 1981
- The rotational spectrum, nuclear spin—spin coupling, nuclear quadrupole coupling, and molecular structure of KrHFChemical Physics, 1981
- The rotational spectrum and structure of van der Waals complexes. II. Krypton-hydrogen chlorideChemical Physics, 1980
- Microwave and radio frequency spectrum of XeHClThe Journal of Chemical Physics, 1979
- Chemiluminescence-depletion of vibrational relaxation. Part 2.—HCl(v= 2–4)+ CO2Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 1979
- Radiofrequency and Microwave Spectrum of the Hydrogen Fluoride Dimer; a Nonrigid MoleculeThe Journal of Chemical Physics, 1972
- Infra-red cryogenic studies. Part 6.—Deuterium chloride in argon and other matricesTransactions of the Faraday Society, 1971
- Infra-red cryogenic studies. Part 3.—Hydrogen halides in doped argon matricesTransactions of the Faraday Society, 1969