The charge-transfer contribution to the intensity of hypersensitive trivalent lanthanide transitions
- 1 May 1977
- journal article
- research article
- Published by Taylor & Francis in Molecular Physics
- Vol. 33 (5) , 1239-1246
- https://doi.org/10.1080/00268977700101051
Abstract
By considering the variation of charge-transfer energy and of the intensity parameters across isostructural series it is concluded that charge-transfer mixing is of negligible importance in accounting for the intensity of the hypersensitive transitions of the trivalent lanthanides. The experimental relationship between hypersensitive transition intensity and charge-transfer energy found for a particular member of the lanthanide series in various environments can be as satisfactorily explained by the ligand polarization theory as by charge-transfer mixing.Keywords
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