Ruthenium catalysed synthesis of unsaturated acetals and aldehydes via C–C bond coupling of alkynes with allyl alcohol
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 22,p. 2551-2552
- https://doi.org/10.1039/c39940002551
Abstract
Terminal alkynes and allyl alcohol are coupled, with carbon–carbon bond formation, in the presence of a RuIV(C5Me5) catalyst, to give γδ-unsaturated acetals and with [{RuCl(C5Me5)}4] or [RuCl(cod)(C5Me5)] preferentially to produce the branched γ,δ-unsaturated aldehydes.Keywords
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