First examples of seleno-Claisen rearrangements of allyl vinyl selenides
- 1 January 1992
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 22,p. 1680-1681
- https://doi.org/10.1039/c39920001680
Abstract
Allyl vinyl selenides easily undergo a [3.3] sigmatropic rearrangement under mild conditions to give γ-unsaturated reactive selenocarbonyl compounds, which can be trapped by cyclopentadiene or water.Keywords
This publication has 17 references indexed in Scilit:
- Recent Synthetic Developments in Thiocarbonyl ChemistryPhosphorus, Sulfur, and Silicon and the Related Elements, 1991
- Diastereocontrol of thio-Claisen rearrangement induced by an adjacent hydroxy-substituted chiral centreJournal of the Chemical Society, Chemical Communications, 1989
- Stereochimie de la deprotonation et de la reaction d'aldolisation des dithioestersTetrahedron, 1985
- Introduction of two carbon appendages at a carbonyl carbon. Application to double chain branching and spiro annulation operationsJournal of the American Chemical Society, 1970
- The thio-Claisen rearrangements of allyl and propargyl 4-quinolyl sulfidesTetrahedron Letters, 1969
- Alkylation of carbonyl and thiocarbonyl compounds: Claisen‐rearrangement of substituted vinyl allyl sulfidesRecueil des Travaux Chimiques des Pays-Bas, 1968
- Thio-Claisen rearrangement. Further studies of the thermal rearrangement of .beta.-methylallyl phenyl sulfideThe Journal of Organic Chemistry, 1967
- The Thio-Claisen Rearrangement. The Mechanism of Thermal Rearrangement of Allyl Aryl SulfidesThe Journal of Organic Chemistry, 1966
- The Formation of Thiachroman as a Major Product in the Claisen Rearrangement of Allyl Phenyl Sulfide1The Journal of Organic Chemistry, 1963
- The Claisen Rearrangement of Allyl Aryl SulfidesJournal of the American Chemical Society, 1962