Synthesis and structure of the first trans-1,2-dihydro-1,2,3-triphosphete–tungsten complex
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 20,p. 2113-2114
- https://doi.org/10.1039/c39950002113
Abstract
Thermal decomposition of the 2H-azaphosphirene complex 1 in the presence of kinetically stabilised phosphalkynes 2a,b yields the 1H-diphosphirene complex 4a and the 1,2-dihydro-1,2,3-triphosphete complex 5; for the latter the overall reaction may be described as an insertion of a phosphanediyl complex into a ring bond of a transiently formed 1H-diphosphirene complex, with loss of one pentacarbonyltungsten moiety.Keywords
This publication has 1 reference indexed in Scilit:
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