Abstract
We report x‐ray photoelectron emission measurements of the ternary chalcopyrite compound CuAlS2. The measurements include the core electron levels and the valence band density‐of‐states distribution. The structure of the valence band includes the s band located 8.5 eV below the valence band edge, the p band located 3.0 eV below, and the copper d band located 0.7 eV below. Our measurements also indicate a higher degree of hybridization between the d and p bands than was observed in AgGaS2.