Preparation of Site-Selective Ion-Exchange Resins
- 1 March 1991
- journal article
- research article
- Published by Taylor & Francis in Separation Science and Technology
- Vol. 26 (3) , 345-354
- https://doi.org/10.1080/01496399108050476
Abstract
Ion-exchange resins were prepared by copolymerization of styrenic monomers with metal ion complex compounds bearing polymerizable ligands. Removal of the metal ions by acid washing produced sites in the resins which contained ligands configured to match the bonding characteristics of the ions used in their construction. This template procedure was performed with Ni2+ and Cu2- ions, and comparisons were made of exchange capacities and equilibrium constants for templated and untemplated resins. Templated resins showed order of magnitude capacity preferences for the ion used in their preparation. Equilibrium constants were found to be inversely related to capacities.Keywords
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