5f-band width and resonant photoemission of uranium intermetallic compounds

Abstract
New experimental results and theoretical arguments are used in conjunction with previously published data to demonstrate that resonant photoemission (RPS) does not provide a reliable measure of the occupied 5f density of states in uranium intermetallic compounds. We implicate a resonant Auger process in this phenomenon and argue that RPS measurements (in conjunction with x-ray photoemission spectroscopy data) in this context are more useful as a qualitative guide to U 5f-ligand hybridization.