Base-catalysed asymmetric hydroamination/cyclisation of aminoalkenes utilising a dimeric chiral diamidobinaphthyl dilithium salt
- 11 April 2006
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- Vol. 37 (21) , 2221-2223
- https://doi.org/10.1039/b518360j
Abstract
A dimeric proline derived diamidobinaphthyl dilithium salt represents the first example of a chiral main group metal based catalyst for asymmetric hydroamination/cyclisation reactions of aminoalkenes.Keywords
This publication has 52 references indexed in Scilit:
- Catalytic asymmetric hydroamination of non-activated olefinsOrganic & Biomolecular Chemistry, 2005
- Transition Metal‐Catalyzed Asymmetric Hydroamination of Alkenes (AHA)Advanced Synthesis & Catalysis, 2005
- Organolanthanide-Catalyzed HydroaminationAccounts of Chemical Research, 2004
- C2-Symmetric Bis(oxazolinato)lanthanide Catalysts for Enantioselective Intramolecular Hydroamination/CyclizationJournal of the American Chemical Society, 2003
- Synthesis and Characterization of New Biphenolate and Binaphtholate Rare‐Earth‐Metal Amido Complexes: Catalysts for Asymmetric Olefin Hydroamination/CyclizationChemistry – A European Journal, 2003
- Biaryl amine ligands for lanthanide catalysed enantioselective hydroamination/cyclisation of aminoalkenesTetrahedron: Asymmetry, 2003
- Chiral-at-metal organolanthanides: enantioselective aminoalkene hydroamination/cyclisation with non-cyclopentadienylsElectronic supplementary information (ESI) available: complete experimental procedures and characterising data for all ligands and complexes, crystal data for [YL2{N(SiMe2H)2}(THF)] and [SmL4{N(SiMe2H)}]. See http://www.rsc.org/suppdata/cc/b3/b305105f/Chemical Communications, 2003
- Base-Catalyzed Hydroamination of Olefins: An Environmentally Friendly Route to AminesAdvanced Synthesis & Catalysis, 2002
- Catalytic Hydroamination of Unsaturated Carbon‐Carbon BondsPublished by Wiley ,2001
- Metal-Initiated Amination of Alkenes and AlkynesChemical Reviews, 1998