Catalytic asymmetric hydroamination of non-activated olefins
- 7 April 2005
- journal article
- emerging area
- Published by Royal Society of Chemistry (RSC) in Organic & Biomolecular Chemistry
- Vol. 3 (10) , 1819-1824
- https://doi.org/10.1039/b418521h
Abstract
Hydroamination is a highly atom-economical process in which an amine N–H functionality is added to an unsaturated carbon–carbon linkage. This potentially highly useful process gives access to various nitrogen-containing basic and fine chemicals as well as naturally occurring alkaloid skeletons. Asymmetric hydroamination reactions promoted by chiral catalysts are particularly attractive. This review highlights recent progress in the development of early transition metal catalysts for the asymmetric hydroamination of non-activated alkenes.Keywords
This publication has 49 references indexed in Scilit:
- Chiral biarylamido/anisole complexes of yttrium in enantioselective aminoalkene hydaroamination/cyclisationDalton Transactions, 2004
- Kinetic resolution of chiral aminoalkenes via asymmetric hydroamination/cyclisation using binaphtholate yttrium complexesElectronic supplementary information (ESI) available: experimental procedures and characterising data for all new complexes and substrates. See http://www.rsc.org/suppdata/cc/b3/b316096c/Chemical Communications, 2004
- Asymmetric Synthesis of β‐Amino Acid and Amide Derivatives by Catalytic Conjugate Addition of Aromatic Amines to N‐AlkenoylcarbamatesEuropean Journal of Organic Chemistry, 2004
- Enantioselective Catalytic Hydroamination of AlkenesAngewandte Chemie International Edition in English, 2003
- Dicationic [(BINAP)Pd(solvent)2]2+[TfO–]2: enantioselective hydroamination catalyst for alkenoyl-N-oxazolidinonesChemical Communications, 2003
- Base-Catalyzed Hydroamination of Olefins: An Environmentally Friendly Route to AminesAdvanced Synthesis & Catalysis, 2002
- Metal-Initiated Amination of Alkenes and AlkynesChemical Reviews, 1998
- The [IrCl(Diphosphine)]2/Fluoride System. Developing Catalytic Asymmetric Olefin HydroaminationJournal of the American Chemical Society, 1997
- Diverse Mechanistic Pathways and Selectivities in Organo-f-Element-Catalyzed Hydroamination. Intermolecular Organolanthanide-Catalyzed Alkyne and Alkene HydroaminationOrganometallics, 1996
- Zur Komplexkatalyse der Aminomethylierung und Aminierung von OlefinenZeitschrift für Chemie, 1986