MODELING OF HYDROPROCESSING REACTIONS
- 1 September 1988
- journal article
- research article
- Published by Taylor & Francis in Chemical Engineering Communications
- Vol. 71 (1) , 53-71
- https://doi.org/10.1080/00986448808940414
Abstract
Langmuir-Hinshelwood-Hougen-Watson rate expressions are developed for the hydroprocessing of quinoline, naphthalene and dibenzothiophene based on batch reactor data at 350°C and at 500 psig. Based on competitive adsorption, the kinetics are extended to binary mixtures of quinoline/naphtha-lene and quinoline/dibenzothiophene. In doing so, the differences in hydrogenation and hydro-genolysis sites are taken into consideration. In all cases, the agreement between the predicted and experimental results are goodKeywords
This publication has 13 references indexed in Scilit:
- Effect of hydrogen pressure on catalytic hydrodenitrogenation of quinolineIndustrial & Engineering Chemistry Process Design and Development, 1986
- Hydrogenation of aromatic hydrocarbons catalyzed by sulfided cobalt oxide-molybdenum oxide/.alpha.-aluminum oxide. Reactivities and reaction networksIndustrial & Engineering Chemistry Process Design and Development, 1981
- Reaction network and kinetics of the vapor-phase catalytic hydrodenitrogenation of quinolineIndustrial & Engineering Chemistry Process Design and Development, 1981
- Catalytic HydrodesulfurizationCatalysis Reviews, 1980
- Process and Catalyst Needs for HydrodenitrogenationCatalysis Reviews, 1979
- Intermediate Reactions in the Catalytic Hydrodenitrogenation of QuinolineIndustrial & Engineering Chemistry Process Design and Development, 1978
- Model discrimination and parameter estimation in heterogeneous catalysisAIChE Journal, 1975
- The mechanism of pyridine hydrogenolysis on molybdenum-containing catalysts II. Hydrogenation of pyridine to piperidineJournal of Catalysis, 1973
- Chemistry and engineering of catalytic hydrodesulfurizationAIChE Journal, 1973
- Determination of Rate Constants for Complex Kinetics ModelsIndustrial & Engineering Chemistry Fundamentals, 1967