An octameric titanium oxo metallacycle with host–guest interactions
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 12,p. 1231-1232
- https://doi.org/10.1039/c39950001231
Abstract
Treatment of TiCl4 with carboxylic acids RCO2H (R = C6F5, CH2C6F5, CH2OC6F5) yields a series of titanium oxo compounds; the X-ray molecular structure of [TiO(O2CC6F5)2] reveals an octameric unit and a unique 16-membered Ti8O8 ring, with two toluene molecules encapsulated above and below the ring in the molecular cavity.Keywords
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