Synthesis of new titanium–oxo cluster compounds: X-ray structure of the tetranuclear oxide [Ti4Cl6(µ2-O2CPh)6(µ3-O)2]
- 1 January 1992
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 11,p. 846-848
- https://doi.org/10.1039/c39920000846
Abstract
Titanium–oxo cluster compounds can be obtained in high yields by the action of carboxylic acids on titanium tetrachloride; X-ray structure analysis of the benzoate derivative [Ti4Cl6(µ2-O2CPH)6(µ3-O)2] reveals the presence of a previously unknown Ti4O2 core structure.Keywords
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