Supramolecular Stereocontrol of Octahedral Metal-Centered Chirality. Ligand Modulation
- 24 April 2004
- journal article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 43 (11) , 3329-3331
- https://doi.org/10.1021/ic049661d
Abstract
By associating chiral labile [FeL3]2+ complexes with TRISPHAT anions, a stereocontrol of the metal-centered chirality is feasible; the sense of the stereoselective induction and its magnitude strongly depends upon the structure of the diimine ligands (L: bpy, phen).Keywords
This publication has 7 references indexed in Scilit:
- Recent developments in chiral anion mediated asymmetric chemistryChemical Society Reviews, 2003
- Ion-Pair-Mediated Asymmetric Synthesis of a Configurationally Stable Mononuclear Tris(diimine)-Iron(II) ComplexAngewandte Chemie International Edition in English, 2002
- Supermolecules by DesignAccounts of Chemical Research, 1999
- Predetermined Chirality at Metal CentersAngewandte Chemie International Edition in English, 1999
- Diastereoselective Ion Pairing of TRISPHAT Anions and Tris(4,4′-dimethyl-2,2′-bipyridine)iron(II)Angewandte Chemie International Edition in English, 1998
- Synthesis and Resolution of the Configurationally Stable Tris(tetrachlorobenzenediolato)phosphate(V) IonAngewandte Chemie International Edition in English, 1997
- Über einen neuen Effekt in Lösungen optisch‐aktiver Substanzen (I. Mitteil.)Berichte der deutschen chemischen Gesellschaft (A and B Series), 1931