Monitoring Multiwalled Carbon Nanotube Exposure in Carbon Nanotube Research Facility
Top Cited Papers
- 1 January 2008
- journal article
- research article
- Published by Taylor & Francis in Inhalation Toxicology
- Vol. 20 (8) , 741-749
- https://doi.org/10.1080/08958370801942238
Abstract
With the increased production and widespread use of multiwalled carbon nanotubes (MWCNTs), human and environmental exposure to MWCNTs is inevitably increasing. Therefore, this study monitored the possible exposure to MWCNT release in a carbon nanotube research laboratory. To estimate the potential exposure of researchers and evaluate the improvement of the workplace environment after the implementation of protective control measures, personal and area monitoring were conducted in an MWCNT research facility where the researchers handled unrefined materials. The number, composition, and aspect ratio of MWCNTs were measured using scanning transmission electron microscopy with an energy-dispersive x-ray analyzer. The gravimetric concentrations of total dust before any control measures ranged from 0.21 to 0.43 mg/m3, then decreased to a nondetectable level after implementing the control measures. The number of MWCNTs in the samples obtained from the MWCNT blending laboratory ranged from 172.9 to 193.6 MWCNTs/cc before the control measures, and decreased to 0.018–0.05 MWCNTs/cc after the protective improvements. The real-time monitoring of aerosol particles provided a signature of the MWCNTs released from the blending equipment in laboratory C. In particular, the number size response of an aerodynamic particle sizer with a relatively high concentration in the range of 2 to 3 μ m in aerodynamic diameter revealed the evidence of MWCNT exposure. The black carbon mass concentration also increased significantly during the MWCNT release process. Therefore, the present study suggests that the conventional industrial hygiene measures can significantly reduce exposure to airborne MWCNTs and other particulate materials in a nano research facility.Keywords
This publication has 14 references indexed in Scilit:
- Penetration of 4.5nm to aerosol particles through fibrous filtersJournal of Aerosol Science, 2007
- Generation and investigation of airborne silver nanoparticles with specific size and morphology by homogeneous nucleation, coagulation and sinteringJournal of Aerosol Science, 2006
- In-Flight Kinetic Measurements of the Aerosol Growth of Carbon Nanotubes by Electrical Mobility ClassificationThe Journal of Physical Chemistry B, 2006
- Carbon Nanotubes: A Review of Their Properties in Relation to Pulmonary Toxicology and Workplace SafetyToxicological Sciences, 2006
- Comparing aerosol surface-area measurements of monodisperse ultrafine silver agglomerates by mobility analysis, transmission electron microscopy and diffusion chargingJournal of Aerosol Science, 2005
- In-flight size classification of carbon nanotubes by gas phase electrophoresisNanotechnology, 2005
- Black carbon concentrations in California vehicles and estimation of in-vehicle diesel exhaust particulate matter exposuresAtmospheric Environment, 2004
- Personal Exposure to Ultrafine Particles in the Workplace: Exploring Sampling Techniques and StrategiesAnnals of Occupational Hygiene, 2004
- Contribution from indoor sources to particle number and mass concentrations in residential housesAtmospheric Environment, 2004
- Exposure to Carbon Nanotube Material: Aerosol Release During the Handling of Unrefined Single-Walled Carbon Nanotube MaterialJournal of Toxicology and Environmental Health, Part A, 2004