Abstract
Results for β‐FeSi2 obtained from self‐consistent calculations with the augmented spherical wave ab initio band‐structure method are presented. In accordance with several experimental findings, β‐FeSi2 is found to be a semiconductor. The calculated gap is 0.44 eV and is indirect. The smallest direct gap is 0.46 eV and has a vanishingly small oscillator strength. The first across‐gap transition with an appreciable oscillator strength has a corresponding energy gap of 0.77 eV.

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