The microwave spectrum of the AlO radical

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Abstract
The rotational spectrum of the aluminum monoxide radical in the ground electronic state X 2Σ+ was observed in the millimeter‐ and submillimeter‐wave region. Aluminum monoxide radicals were generated directly in a flow reactor absorption cell by the reaction of N2O with aluminum vaporized from a high‐temperature crucible. The observed spectrum was analyzed to yield molecular constants including the rotational constant, centrifugal distortion constant, spin–rotation interaction constant, magnetic hyperfine interaction constants, and nuclear quadrupole coupling constant.

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