Isomers of Chloro(triarylsilyl)hydridorhodium(III) Complexes, mer-RhCl(H)(SiAr3)(PMe3)3. Relevance of Their Structures to Reductive Elimination of ClSiAr3
- 1 April 1998
- journal article
- Published by American Chemical Society (ACS) in Organometallics
- Vol. 17 (9) , 1868-1872
- https://doi.org/10.1021/om970846k
Abstract
No abstract availableThis publication has 20 references indexed in Scilit:
- Structure and Chemical Properties of Chlorohydrido(diarylsilyl)rhodium(III) Complexes,mer-RhCl(H)(SiHAr2)(PMe3)3. Thermally Induced Chloro Transfer from Rhodium to Silicon in the Complexes and Silane ExchangeOrganometallics, 1997
- Si–H and Si–C Bond Activation of a Triorganosilane Promoted by [RhCl{P(i-Pr)3}2]. Synthesis and Structure of a Dinuclear Rh(IV) Complex with μ-Silylene LigandsBulletin of the Chemical Society of Japan, 1997
- Unique intramolecular exchange between H of SiHPh2 and SAr in [RhH(SiHPh2)(SAr)(PMe3)3]Journal of the Chemical Society, Chemical Communications, 1995
- Silicon-hydrogen, silicon-silicon, and carbon-hydrogen bond activation by coordinatively unsaturated rhodium phosphine RhCl(PH3)2: ab initio molecular orbital studyJournal of the American Chemical Society, 1993
- The mechanisms of the reactions between hydrido-complexes and diazonium salts. Part 2. The reactions of cis,mer-[RhHCl2(PEtPh2)3]J. Chem. Soc., Dalton Trans., 1985
- A new synthesis of silyliridium hydridesJournal of the Chemical Society D: Chemical Communications, 1969
- Homogeneous Catalysis. II. The Mechanism of the Hydrosilation of Olefins Catalyzed by Group VIII Metal Complexes1Journal of the American Chemical Society, 1965
- The Effect of Polar Substituents on the Alkali-catalyzed Hydrolysis of Triorganosilanes1Journal of the American Chemical Society, 1961
- The Reaction of Sodium with Organosilanes at Elevated TemperaturesJournal of the American Chemical Society, 1952
- Mechanism of the Alkaline Cleavage of Silicon—Hydrogen Bonds: Temperature Coefficients of the Rate of Cleavage of Several TrialkylsilanesJournal of the American Chemical Society, 1947