Time-Dependent Reorientation Probabilities and Molecular Relaxation
- 15 December 1967
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 47 (12) , 4879-4883
- https://doi.org/10.1063/1.1701731
Abstract
This article considers situations in which the probability of molecular reorientation is governed by a secondary, time‐dependent process. A ``projection technique'' for computing reorientational correlation functions in these situations is described, together with a ``simple defect'' model of molecular relaxation. The effects of different types of secondary time‐dependent processes on the observable correlation time distribution are discussed.Keywords
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