Composition of the first coordination sphere of Ni2+ in concentrated aqueous NiBr2 solutions by x-ray diffraction
- 1 December 1985
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 83 (11) , 5797-5801
- https://doi.org/10.1063/1.449659
Abstract
Two concentrated solutions of NiBr2 have been examined by x‐ray diffraction. The Fourier transformed scattering data indicate inner complex formation between Ni2+ and Br− ions. Average numbers of bonded bromide ions per nickel atom have been determined for each solution and the reliability of the complexation numbers as well as of the other structural parameters has been critically examined.Keywords
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