Synthesis and Reactions of P-Rich Silylphosphanes
- 1 March 1987
- journal article
- research article
- Published by Taylor & Francis in Phosphorus and Sulfur and the Related Elements
- Vol. 30 (1-2) , 385-388
- https://doi.org/10.1080/03086648708080601
Abstract
The formation of P-rich compounds like (Me3Si)3P7 1 and P4(SiMe2)3 2 generated from Na/K-alloy, white phosphorus, Me3SiCl and Me2SiCl2, resp., or the formation of 1 from P4, lithiumalkyles and Me3SiCl on the other hand occurs in several reaction steps1.Keywords
This publication has 3 references indexed in Scilit:
- Zur Bildung cyclischer Silylphosphane Umsetzung von Li‐Phosphiden mit R2SiCl2 (R = Me, Et, t‐Bu)Zeitschrift für anorganische und allgemeine Chemie, 1986
- SilylphosphanesComments on Inorganic Chemistry, 1982
- Alkali-phosphorverbindungen und ihr reaktives verhalten : XXX. Zur P-H- und As-H-acidität primärer und sekundärer phosphine bzw. arsineJournal of Organometallic Chemistry, 1965