Preparation and aromatization of poly‐1,3‐cyclohexadiene. II
- 1 June 1963
- journal article
- research article
- Published by Wiley in Journal of Polymer Science Part A: General Papers
- Vol. 1 (6) , 2057-2065
- https://doi.org/10.1002/pol.1963.100010623
Abstract
Further work on the polymerization of 1,3‐cyclohexadiene by the action of Zieglertype catalysis and by cationic initiation has been carried out and polymers with an inherent viscosity of 0.1–0.19 have been obtained consistently. Dehydrogenation of the poly‐1,3‐cyclohexadiene by halogenation followed by pyrolysis has given good conversion to a polyphenyl which has some units which are incompletely aromatized. This polymer has very good heat stability but is not a useful polymer for plastic purposes.Keywords
This publication has 3 references indexed in Scilit:
- Vinyl Polymerization XLVII. Polymerization of Acenaphthylene with Ziegler-Type CatalystsBulletin of the Chemical Society of Japan, 1961
- Preparation and Aromatization of Poly-1,3-cyclohexadiene1Journal of the American Chemical Society, 1959
- Preparation of titanium tetrachloride of high purityJournal of Research of the National Bureau of Standards, 1955