Abstract
The probability for producing K vacancies in violent ion-atom collisions has been found to depend not only on the impact parameter, but also on the impact velocity and the number of vacancies in the atomic 2p subshells of the particles prior to the collision. This indicates that the K-electron promotion mechanism is different from the L2,3-promotion mechanism determined for Z1Ar collisions. The K vacancies are almost exclusively produced in the lower-Z collision partner.