Molecular dynamics in liquid cyclopropane - I. — Self-diffusion Measurements by Quasielastic Neutron Scattering and N.M.R. Spin Echo
- 1 January 1977
- journal article
- Published by EDP Sciences in Journal de Physique
- Vol. 38 (11) , 1417-1422
- https://doi.org/10.1051/jphys:0197700380110141700
Abstract
The translational diffusion of liquid cyclopropane was studied by quasielastic neutron scattering (Q.N.S.) and by N.M.R. spin-echo in the temperature range 155-297 K. The values of the self-diffusion coefficient derived from the two techniques was the same within experimental accuracy (D = 0.78 x 10-5 cm2 s-1 at 155 K, and D = 9.2 x 10-5 cm2 s-1 at 297 K). This shows that high-resolution Q.N.S. measurements at small momentum transfer give accurate information in the hydrodynamic regionKeywords
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