Photoemission studies of mixed valency:Ce(Ag0.3Pd0.7)3, CePd3, and CeRh3
- 15 April 1982
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 25 (8) , 5530-5533
- https://doi.org/10.1103/physrevb.25.5530
Abstract
Photoemission studies of a Ce-compound system previously identified as spanning the entire mixed-valent range are presented. Valence-band spectra of , Ce, Ce, and La suggest that Ce in Ce is 3 + -like while in Ce it is more 4 + -like. However, resonant photoemission and partial-yield spectra show that Ce in Ce is not in a formal configuration as has been widely accepted.
Keywords
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