Thermal Decomposition of 4,4‐Dimethylpentene−1 in a Single‐Pulse Shock Tube
- 1 April 1967
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 46 (7) , 2817-2822
- https://doi.org/10.1063/1.1841120
Abstract
4,4‐Dimethylpentene−1 has been pyrolyzed in a single‐pulse shock tube. The initial process is apparently the breaking of the allylic carbon—carbon bond. The rate expressions for the reaction has been found to be Assuming no activation energy for the recombination process this leads to a value of 12 kcal for the allylic resonance energy.
Keywords
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