Velocity-dependent isotope fractionation in secondary-ion emission

Abstract
The formation of secondary ions is subject to isotopic fractionation (differing ionization probabilities for two isotopes) that depends linearly on the inverse velocity of the ejected ions. Theoretically, such a correlation follows directly from an exponential dependence of the ionization probability P on v1, P∝exp(-v0/v). The parameter v0, derived from the experiment, amounts to ∼2×106 cm/sec for B, Si, and Ca ions.

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