Formation of [(L)Ni(μ2-S)x{Fe(CO)3}x] adducts (x = 1 or 2): analogues of the active site of [NiFe] hydrogenase
- 24 November 2005
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 3,p. 317-319
- https://doi.org/10.1039/b509798c
Abstract
The binuclear [Ni(L)Fe(CO)3], 1, and trinuclear [Ni(L){Fe(CO)3}2], 2, complexes adopt unusual structural motifs whereby Fe(CO)3 units bind to [Ni(L)] via μ2-S bridging modes, CN imine π-bonds and potential Ni–Fe bonding interactions.Keywords
This publication has 45 references indexed in Scilit:
- The Synthesis and Electronic Structure of a Novel [Ni‘S4’Fe2(CO)6] Radical Cluster: Implications for the Active Site of the [NiFe] HydrogenasesChemistry – A European Journal, 2004
- Hydrogenases: active site puzzles and progressCurrent Opinion in Chemical Biology, 2004
- Assembly of Dicobalt(III) Complexes Incorporating Di‐μ‐thiophenolate MoietiesEuropean Journal of Inorganic Chemistry, 2003
- Structure and Electronic Properties of [Ni(dsdm){Fe(CO)3}2], an Unusual, Triangular Nickel Diiron CompoundEuropean Journal of Inorganic Chemistry, 2003
- A New Method for Incorporating Thiolate Donors into a Metal Coordination Sphere. Synthesis and Crystal Structures of the First Nickel Complexes of an N3S LigandInorganic Chemistry, 1999
- Oxygen Capture by Sulfur in Nickel ThiolatesAccounts of Chemical Research, 1998
- [N,N'-Bis(2-thiobenzylidene)-1,2-phenylenediaminato]nickel(II)Acta Crystallographica Section C Crystal Structure Communications, 1997
- Crystal structure of the nickel–iron hydrogenase from Desulfovibrio gigasNature, 1995
- An Efficient One-Pot Synthesis of 1,2-Benzenedithiol from BenzenethiolSynthesis, 1992
- A New Synthetic Route and the Structural Analysis of Ni(tsalen). (N,N′-Ethylenebis(thiosalicylidenaminato))nickel(II)Chemistry Letters, 1989