Molecular Solids as Ligands in Organometallic Chemistry: [CpTi6Na7F19·2.5thf] (Cp* C5Me5) and [CpTi4Mg2F12·7thf], Links Between Ionic Solids and Organometallic Compounds
- 17 March 1994
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 33 (5) , 555-556
- https://doi.org/10.1002/anie.199405551
Abstract
Central NaF and MgF2 frameworks are present in the title compounds obtained from the reaction of [Cp*TiF3] (Cp C5Me5) with elemental sodium and magnesium, respectively. In these reactions TiIV is reduced to TiIII. The Cp*Ti units function as organometallics shields around the cagelike core and are responsible for the high solubility of the compounds.Keywords
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