Zur kenntnis der ätherischen öle 6. Mitteilung [1] die thermische cyclisation des (−)‐(r)‐Linalools. Die struktur der Plinole und einiger derivate mit Iridan‐Gerüst [2]

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Abstract
On heating linalool, all the four possible diastereomeric plinols are formed by way of an intramolecular Alder “ene”‐synthesis. The knowledge of their absolute configuration, shown to be 2A‐2D, allows a discussion of the stereochemical course of this reaction.