Order-Parameter Exponentof a Binary Liquid Mixture at a Boundary
- 27 October 1986
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review Letters
- Vol. 57 (17) , 2191-2194
- https://doi.org/10.1103/physrevlett.57.2191
Abstract
We have measured the transition from partial to complete wetting of Pyrex capillaries in a critical mixture of 2,6-lutidine and water with different amounts of dissolved potassium chloride. With increasing concentration of KCl the difference between the critical and wetting temperatures decreases. At a concentration of 7.3 × mol/l KCl we observe only partial wetting and can thus determine the difference between the critical exponent of the order parameter, , at the (Pyrex) boundary, and , in the bulk, from the capillary rise close to . The result is in good agreement with theoretical predictions.
Keywords
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