EPR investigations of thermal decomposition of nitramines: I. primary nitroxide radicals from RDX
- 1 June 1983
- journal article
- research article
- Published by Taylor & Francis in Journal of Energetic Materials
- Vol. 1 (2) , 127-132
- https://doi.org/10.1080/07370658308010628
Abstract
We have observed that the free radical produced from solid RDX undergoing thermal decomposition can also be produced in RDX-sulfolane solutions. Under milder conditions, an earlier free radical is produced which is identified as the known nitroxide. Pronounced radical-cage effects are observed.Keywords
This publication has 2 references indexed in Scilit:
- Mise en évidence par R.P.E. d'espèces intermédiaires radicalaires intervenant dans la décomposition de quelques nitramines irradiéesInternational Journal for Radiation Physics and Chemistry, 1972
- ESR Studies of Unsubstituted Cyclic Nitroxides in SolidsThe Journal of Chemical Physics, 1972