Total Synthesis of Jimenezin via an Intramolecular Allylboration
- 25 July 2006
- journal article
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 8 (17) , 3829-3831
- https://doi.org/10.1021/ol0614471
Abstract
An efficient total synthesis of the annonaceous acetogenin jimenezin was achieved. The key steps used were a highly stereoselective intramolecular allylboration to establish the tetrahydropyran ring and an intramolecular Williamson reaction to close the tetrahydrofuran ring.Keywords
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