Über die Pyrolyse von Pent‐1‐en‐3,3‐d2
- 1 January 1983
- journal article
- research article
- Published by Wiley in Journal für Praktische Chemie
- Vol. 325 (3) , 375-381
- https://doi.org/10.1002/prac.19833250305
Abstract
On the Pyrolysis of Pent‐1‐ene‐3,3‐d2The distribution of deuterium in the main products of the thermal decomposition of pent‐1‐ene‐3,3‐d2 at 550 to 650°C was studied and interpreted. The results include conclusions on kinetic isotope effects, on relative reactivities of different CH‐bonds, and on the importance of nonterminal radical addition. It is shown that butadiene‐d2 detected in the isotopically labeled butadiene fraction is a reliable target molecule for the homoallylic rearrangement of the pent‐1‐ene‐4‐yl‐3,3‐d2 radical.Keywords
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